Wang Chen-Yi
Department of Chemistry, Huzhou University, Huzhou 313000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m1008. doi: 10.1107/S1600536811025116. Epub 2011 Jun 30.
The title mononuclear cobalt(III) complex, [Co(C(14)H(19)N(2)O(2))(C(8)H(7)O(2))(NCS)], was obtained by the reaction of 2-acetyl-phenol, 2-(morpholin-4-yl)ethyl-amine, ammonium thio-cyan-ate and cobalt nitrate in methanol. The Co(III) atom is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two O atoms of the 2-acetyl-phenolate anion and one thio-cyanate N atom. This results in a fairly regular fac-CoN(3)O(3) octa-hedral coordination geometry for the metal ion. The dihedral angle between the two benzene rings is 88.3 (3)°.
标题单核钴（III）配合物[Co(C₁₄H₁₉N₂O₂)(C₈H₇O₂)(NCS)]是通过2-乙酰基苯酚、2-(吗啉-4-基)乙胺、硫氰酸铵和硝酸钴在甲醇中反应得到的。Co(III)原子由三齿席夫碱配体的一个酚盐O原子、一个亚胺N原子和一个胺N原子、2-乙酰基酚盐阴离子的两个O原子以及一个硫氰酸根N原子配位。这导致金属离子具有相当规则的面式CoN₃O₃八面体配位几何构型。两个苯环之间的二面角为88.3 (3)°。
