磷迈克尔加成产物{（叔丁基氨基）磷（μ-N-叔丁基）₂磷（=N-叔丁基）-C（=CH₂）CH（对甲氧基苯基）-磷酰基[（OCH₂C（CH₃）₂CH₂O）]}
The Phospha-Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)-C(=CH(2))CH(p-CH(3)O-C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}.
作者信息
Gangadhararao G, Venu Srinivas
机构信息
School of Chemistry, University of Hyderabad, Hyderabad 500 046, India.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1212-3. doi: 10.1107/S1600536811014127. Epub 2011 Apr 29.
The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butyl-amino)-2-(tert-butyl-imino)-1,3,2λ(5),4-diaza-diphosphetidin-2-yl]-1-(4-meth-oxy-phen-yl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ(5)-dioxaphosphinan-2-one, C(31)H(57)N(4)O(4)P(3), was synthesized from the Phospha-Michael addition reaction of cyclo-diphos-pha-zane (t-BuNH)P(μ-Nt-Bu) and allenyl-phospho-nate [(OCH(2)C(CH(3))(2)CH(2)O)P(O)C(p-CH(3)O-C(6)H(4))=C=CH(2)]. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules. The structure exhibits pseudosymmetry but attempts to solve it in a higher (monoclinic) space group were unsuccessful.
标题化合物2-{2-[1,3-二叔丁基-4-(叔丁基氨基)-2-(叔丁基亚氨基)-1,3,2λ(5),4-二氮杂二磷杂环丁烷-2-基]-1-(4-甲氧基苯基)丙-2-烯-1-基}-5,5-二甲基-1,3,2λ(5)-二氧杂磷杂环己烷-2-酮，化学式为C(31)H(57)N(4)O(4)P(3)，由环二磷氮烷(t-BuNH)P(μ-Nt-Bu)与烯丙基膦酸酯[(OCH(2)C(CH(3))(2)CH(2)O)P(O)C(p-CH(3)O-C(6)H(4))=C=CH(2)]通过磷迈克尔加成反应合成。晶体中，N-H⋯O和C-H⋯O氢键连接分子。该结构呈现假对称性，但尝试在更高的（单斜）空间群中解析其结构未成功。
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