Shakuntala K, Foro Sabine, Gowda B Thimme
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1252. doi: 10.1107/S1600536811015108. Epub 2011 Apr 29.
In the crystal of the title compound, C(12)H(10)ClNO(2)S, the asymmetric unit contains two independent mol-ecules. The N-C bonds in the C-SO(2)-NH-C segments have gauche torsions with respect to the S=O bonds. The mol-ecules are twisted at the S atoms with C-SO(2)-NH-C torsion angles of -53.8 (3) and -63.4 (3)° in the two mol-ecules. The benzene rings are tilted relative to each other by 69.1 (1) and 82.6 (1)°. The dihedral angle between the sulfonyl benzene rings of the two independent mol-ecules is 23.7 (2)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.
在标题化合物C₁₂H₁₀ClNO₂S的晶体中,不对称单元包含两个独立的分子。C-SO₂-NH-C片段中的N-C键相对于S=O键具有 gauche扭转。分子在S原子处发生扭曲,两个分子中C-SO₂-NH-C扭转角分别为-53.8 (3)°和-63.4 (3)°。苯环彼此倾斜69.1 (1)°和82.6 (1)°。两个独立分子的磺酰苯环之间的二面角为23.7 (2)°。晶体结构的特征是通过N-H⋯O氢键连接的反演相关二聚体。