Shakuntala K, Foro Sabine, Gowda B Thimme
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1536. doi: 10.1107/S160053681101960X. Epub 2011 May 28.
In the title compound, C(14)H(14)ClNO(2)S, the N-H bond points away from the dimethyl-phenyl ring plane. The mol-ecule is twisted at the S atom, with a C-SO(2)-NH-C torsion angle of -75.5 (2)°. The two aromatic rings are tilted relative to each other by 63.3 (1)°. The Cl atom on the chloro-benzene ring is disordered over two sites with site-occupation factors of 0.59 (3) and 0.41 (3), respectively. The crystal structure features inversion-related dimers linked by inter-molecular N-H⋯O hydrogen bonds.
在标题化合物C₁₄H₁₄ClNO₂S中，N - H键远离二甲基苯环平面。分子在S原子处发生扭曲，C - SO₂ - NH - C扭转角为 - 75.5 (2)°。两个芳环彼此倾斜63.3 (1)°。氯苯环上的Cl原子在两个位置上无序，占位因子分别为0.59 (3)和0.41 (3)。晶体结构具有通过分子间N - H⋯O氢键连接的反演相关二聚体。
