三氯（4-甲基苄基）双（1H-吡唑-κN）锡（IV）
Trichlorido(4-methyl-benz-yl)bis-(1H-pyrazole-κN)tin(IV).
作者信息
Keng Thy Chun, Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m659. doi: 10.1107/S1600536811015698. Epub 2011 May 7.
Abstract
The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa-hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn-N bond that is trans to the Sn-C bond is shorter than the Sn-N bond trans to the Sn-Cl bond. Weak N-H⋯Cl hydrogen bonds link adjacent mol-ecules, generating a double chain running along the c axis.
摘要
在标题化合物[Sn(C₈H₉)Cl₃(C₃H₄N₂)₂]中，六配位的Sn(IV)原子呈八面体配位。氮杂环的N原子彼此顺式排列。与Sn-C键反式的Sn-N键比与Sn-Cl键反式的Sn-N键短。弱的N-H⋯Cl氢键连接相邻分子，形成沿c轴延伸的双链。
相似文献
1
Trichlorido(4-methyl-benz-yl)bis-(1H-pyrazole-κN)tin(IV).三氯（4-甲基苄基）双（1H-吡唑-κN）锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m659. doi: 10.1107/S1600536811015698. Epub 2011 May 7.
2
(2,2'-Bipyridine-κN,N')dichloridobis(4-fluoro-benz-yl)tin(IV).（2,2'-联吡啶-κN,N'）二氯双（4-氟苄基）锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m658. doi: 10.1107/S1600536811015686. Epub 2011 May 7.
3
Bis(μ-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[chloridomethyl-phenyl-tin(IV)].双（μ-喹啉-8-醇根）-κN，O：O；κO：N，O-双-[氯甲基-苯基-锡（IV）]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m964. doi: 10.1107/S1600536810027765.
4
Chloridodiphen-yl{[1-(1,3-thia-zol-2-yl-κN)ethyl-idene]-4-phenyl-thio-semicarbazidato-κN,S}tin(IV) methanol monosolvate.氯代二苯基{[1-(1,3-噻唑-2-基-κN)亚乙基]-4-苯基硫代氨基脲合-κN,S}锡(IV) 甲醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1409-10. doi: 10.1107/S1600536811037627. Epub 2011 Sep 30.
5
n-Butyl-dichlorido(2-{(1E)-1-[2-(pyridin-2-yl)hydrazin-1-yl-idene]eth-yl}phenolato)tin(IV).正丁基 - 二氯（2 - {（1E）-1 - [2 - （吡啶 - 2 - 基）肼 - 1 - 亚基]乙基}苯酚根）锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):m1412-3. doi: 10.1107/S1600536810040572.
6
Trichlorido{2-dimeth-oxy-methyl-4-methyl-6-[(quinolin-8-yl)imino-meth-yl]phenolato-κN,N',O}tin(IV).三氯{2-二甲氧基甲基-4-甲基-6-[(喹啉-8-基)亚氨基甲基]苯酚根-κN,N',O}锡(IV)
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m208. doi: 10.1107/S1600536812002528. Epub 2012 Jan 31.
7
Aqua-bis-(4-chloro-benz-yl)bis-(nicotinato-κO,O')tin(IV).水合双（4-氯苄基）双（烟碱酸根-κO，O'）锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m662. doi: 10.1107/S1600536811015728. Epub 2011 May 7.
8
Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-κN,N')tin(IV).二氯双(4-甲基苄基)(1,10-菲咯啉-κN,N')锡(IV)
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 17;66(Pt 3):m304. doi: 10.1107/S1600536810005672.
9
(2-{[1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-4-chloro-phenolato-κN,O,O')dibutyl-tin(IV).（2-{[1,1-双（羟甲基）-2-氧化乙基亚氨基甲基]-4-氯苯酚根合-κN,O,O'}二丁基锡（IV））
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 31;66(Pt 4):m482. doi: 10.1107/S1600536810011384.
10
Di-chlorido-diphenyl-bis-(thio-urea-κS)tin(IV).二氯二苯基双（硫脲-κS）锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 12;69(Pt 10):m539-40. doi: 10.1107/S1600536813024343. eCollection 2013.
本文引用的文献
1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Zotero 插件