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二（1-甲基-哌啶鎓）四氯合铜（II）酸盐

Bis(1-methyl-piperidinium) tetra-chlorido-cuprate(II).

作者信息

Reynolds Bryan J, Bond Marcus R

机构信息

Department of Chemistry, Southeast Missouri State University, Cape Girardeau, MO 63701, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m725-6. doi: 10.1107/S1600536811016382. Epub 2011 May 7.

DOI:10.1107/S1600536811016382
PMID:21754622
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120374/
Abstract

The structure of the title compound, (C(6)H(14)N)(2)[CuCl(4)], consists of two inequivalent 1-methyl-piperidinium cations and a flattened tetra-hedral CuCl(4) anion. Each organic cation exhibits a chair conformation with the methyl group in the equatorial position. They are segregated into alternating layers parallel to (100) and stacked along [100]. The first cation is arranged in parallel stacks in a herringbone pattern with rows of CuCl(4) anions fitting between the stacks and with a Cl(-) ion directed into the inter-ior of the layer. The second organic cation forms distorted hcp layers that separate the other organic cation/CuCl(4) slabs. N-H⋯Cl hydrogen bonding between the cations and the anions consolidates the crystal packing.

摘要

标题化合物(C₆H₁₄N)₂[CuCl₄]的结构由两个不等价的1-甲基哌啶鎓阳离子和一个扁平的四面体[CuCl₄]²⁻阴离子组成。每个有机阳离子呈现椅式构象，甲基处于赤道位置。它们被分隔成平行于(100)的交替层，并沿[100]堆积。第一个阳离子以人字形图案排列成平行堆叠，[CuCl₄]²⁻阴离子行位于堆叠之间，且一个Cl⁻离子指向层内部。第二个有机阳离子形成扭曲的六方密堆积层，将其他有机阳离子/[CuCl₄]²⁻板层分隔开。阳离子与阴离子之间的N-H⋯Cl氢键巩固了晶体堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94e2/3120374/5faa344be633/e-67-0m725-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94e2/3120374/7d58cba2552c/e-67-0m725-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94e2/3120374/5faa344be633/e-67-0m725-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94e2/3120374/7d58cba2552c/e-67-0m725-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94e2/3120374/5faa344be633/e-67-0m725-fig2.jpg

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本文引用的文献

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[CuCl3(H2O)](-) complexes aggregated to form hydrate columns in methyl-substituted pyridinium or piperidinium salts.[CuCl₃(H₂O)]⁻配合物聚集形成水合物柱，存在于甲基取代的吡啶鎓盐或哌啶鎓盐中。
Acta Crystallogr C. 2011 Jun;67(Pt 6):m185-94. doi: 10.1107/S0108270111017306. Epub 2011 May 18.
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A short history of SHELX.SHELX简史。
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