六氯铟(III)酸双(二亚乙基三胺)钴(III)
Bis(diethyl-enetriamine)-cobalt(III) hexa-chloridoindate(III).
作者信息
Wu Qihui, Chen Shangwen, Zhang Cailing, Zhi Xia, Chen Zelin
机构信息
Department of Materials and Chemical Engineering, Ministry of Education Key Laboratory of Application Technology of Hainan, Superior Resources Chemical Materials, Hainan University, Haikou 570228, Hainan Province, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m731. doi: 10.1107/S1600536811016758. Epub 2011 May 7.
The title compound, [Co(C(4)H(13)N(3))(2)][InCl(6)], was synthesized under hydro-thermal conditions. In the cation, the Co-N bond lengths lie in the range 1.967 (2)-1.9684 (15) Å. In the anion, the In(III) atom is coordinated by six Cl atoms resulting in a slightly distorted octa-hedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N-H⋯Cl hydrogen bonds between cations and anions consolidate the crystal packing.
标题化合物[Co(C₄H₁₃N₃)₂][InCl₆]是在水热条件下合成的。在阳离子中，Co-N键长在1.967(2) - 1.9684(15) Å范围内。在阴离子中，In(III)原子由六个Cl原子配位，形成略微扭曲的八面体几何构型。两个金属原子都位于点群对称性为2/m的特殊位置上。此外，一个Cl原子和一个N原子位于镜面上。阳离子和阴离子之间的N-H⋯Cl氢键巩固了晶体堆积。
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