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N,N'-双(4-氯苯基)马来酰胺

N,N'-Bis(4-chloro-phen-yl)maleamide.

作者信息

Shakuntala K, Foro Sabine, Gowda B Thimme

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1415. doi: 10.1107/S1600536811017636. Epub 2011 May 14.

DOI:10.1107/S1600536811017636
PMID:21754797
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120495/
Abstract

In the crystal of the title compound, C(16)H(12)Cl(2)N(2)O(2), the two C=O groups are anti to each other, while one of them is syn and the other is anti to their adjacent C-H bonds. The two benzene rings are oriented at an inter-planar angle of 56.4 (1)°, while the dihedral angles between the central amide group (N-C-C-C-C-N) and these rings are 3.6 (1) and 54.1 (1)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into infinite chains along the a axis.

摘要

在标题化合物C(16)H(12)Cl(2)N(2)O(2)的晶体中,两个C=O基团彼此呈反式排列,而其中一个与相邻的C-H键呈顺式,另一个呈反式。两个苯环的平面间夹角为56.4 (1)°,而中心酰胺基团(N-C-C-C-C-N)与这些环之间的二面角分别为3.6 (1)°和54.1 (1)°。存在分子内N-H⋯O氢键。在晶体中,分子间N-H⋯O氢键将分子沿a轴连接成无限链。

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