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3-溴-N'-[(2-甲氧基萘-1-基)亚甲基]苯甲酰肼

3-Bromo-N'-[(2-meth-oxy-naphthalen-1-yl)methyl-idene]benzohydrazide.

作者信息

Li He-Bing

机构信息

Department of Chemistry and Life Sciences, Xiangnan University, Chenzhou 423000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1532. doi: 10.1107/S1600536811019349. Epub 2011 May 28.

Abstract

The mol-ecule of the title compound, C(19)H(15)BrN(2)O(2), displays a pseudo-trans conformation about the N-N bond [C-N-N=C torsion angle = 164.7 (2)°]. The dihedral angle between the planes of the benzene ring and the naphthyl system is 70.1 (2)°. In the crystal, mol-ecules are linked into C(4) chains along the c axis by N-H⋯O hydrogen bonds.

摘要

标题化合物C(19)H(15)BrN(2)O(2)的分子围绕N-N键呈现假反式构象[C-N-N=C扭转角 = 164.7 (2)°]。苯环平面与萘基体系平面之间的二面角为70.1 (2)°。在晶体中,分子通过N-H⋯O氢键沿c轴连接成C(4)链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2c40/3120542/5ed37f1f71f2/e-67-o1532-fig1.jpg

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