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（1Z，2E）-N'-{2-氯-1-甲基-2-[2-（4-甲基苯基）肼-1-亚基]亚乙基}-4-甲氧基苯甲酰肼

(1Z,2E)-N'-{2-Chloro-1-methyl-2-[2-(4-methyl-phen-yl)hydrazin-1-yl-idene]ethyl-idene}-4-meth-oxy-benzohydrazide.

作者信息

Abdel-Aziz Hatem A, Ghabbour Hazem A, Hemamalini Madhukar, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o926. doi: 10.1107/S1600536812008367. Epub 2012 Mar 3.

DOI:10.1107/S1600536812008367
PMID:22589991
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3343910/
Abstract

The asymmetric unit of the title compound, C(18)H(19)ClN(4)O(2), contains two mol-ecules, in which the dihedral angles between the benzene rings are 43.60 (12) and 58.65 (13)°. The hydrazine N atoms are twisted slightly out of the planes of the tolyl and meth-oxy-benzene rings: the C-C-N-N and N-N-C-C torsion angles are 171.1 (2) and -174.4 (2)°, respectively, for one mol-ecule and -177.4 (2) and -170.6 (2)°, respectively, for the other. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds into chains propagating along the b-axis direction.

摘要

标题化合物C(18)H(19)ClN(4)O(2)的不对称单元包含两个分子，其中苯环之间的二面角分别为43.60 (12)°和58.65 (13)°。肼基氮原子略微扭曲出甲苯基和甲氧基苯环的平面：对于一个分子，C-C-N-N和N-N-C-C扭转角分别为171.1 (2)°和-174.4 (2)°，对于另一个分子，分别为-177.4 (2)°和-170.6 (2)°。在晶体中，分子通过N-H⋯O和C-H⋯O氢键连接成沿b轴方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bf2/3343910/1eac1c8ea5d8/e-68-0o926-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bf2/3343910/c1dd09ef9611/e-68-0o926-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bf2/3343910/1eac1c8ea5d8/e-68-0o926-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bf2/3343910/c1dd09ef9611/e-68-0o926-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bf2/3343910/1eac1c8ea5d8/e-68-0o926-fig2.jpg

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