Abdel-Aziz Hatem A, Ghabbour Hazem A, Hemamalini Madhukar, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o926. doi: 10.1107/S1600536812008367. Epub 2012 Mar 3.
The asymmetric unit of the title compound, C(18)H(19)ClN(4)O(2), contains two mol-ecules, in which the dihedral angles between the benzene rings are 43.60 (12) and 58.65 (13)°. The hydrazine N atoms are twisted slightly out of the planes of the tolyl and meth-oxy-benzene rings: the C-C-N-N and N-N-C-C torsion angles are 171.1 (2) and -174.4 (2)°, respectively, for one mol-ecule and -177.4 (2) and -170.6 (2)°, respectively, for the other. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds into chains propagating along the b-axis direction.
标题化合物C(18)H(19)ClN(4)O(2)的不对称单元包含两个分子,其中苯环之间的二面角分别为43.60 (12)°和58.65 (13)°。肼基氮原子略微扭曲出甲苯基和甲氧基苯环的平面:对于一个分子,C-C-N-N和N-N-C-C扭转角分别为171.1 (2)°和-174.4 (2)°,对于另一个分子,分别为-177.4 (2)°和-170.6 (2)°。在晶体中,分子通过N-H⋯O和C-H⋯O氢键连接成沿b轴方向延伸的链。