Department of Chemistry, Korea University , Anam-dong, Seongbuk-gu, Seoul 136-701, Korea.
J Nat Prod. 2011 Aug 26;74(8):1817-21. doi: 10.1021/np100942e. Epub 2011 Jul 19.
The total synthesis of optically active phenylbutenoid dimers 1, 3, and ent-3 is described. The key step to access optically active cyclohexene rings was achieved by Diels-Alder reaction of chiral acryloyloxazolinone 9 and phenylbetadiene 10.
本文描述了光学活性苯丁烯二聚体 1、3 和 ent-3 的全合成。通过手性丙烯酰基恶唑啉酮 9 和苯丁二烯 10 的 Diels-Alder 反应，实现了获得光学活性环己烯环的关键步骤。
