萘氧自由基键合铁（salan）配合物促进的仲醇的需氧氧化动力学拆分。
Aerobic oxidative kinetic resolution of secondary alcohols with naphthoxide-bound iron(salan) complex.
机构信息
Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral, Energy Research, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.
出版信息
J Am Chem Soc. 2011 Aug 24;133(33):12937-9. doi: 10.1021/ja204426s. Epub 2011 Aug 1.
PMID:21780821
Abstract
The first general method for iron-catalyzed aerobic oxidative kinetic resolution of secondary alcohols was achieved with good to high enantiomeric differentiation (k(rel) = 7-50). Although iron(salan) complex 1 does not catalyze alcohol oxidation, the naphthoxide-bound iron(salan) complex does.
摘要
首次实现了铁催化的仲醇的有氧动力学拆分的通用方法，具有良好到高的对映体选择性（k(rel) = 7-50）。虽然铁(salan)配合物 1 不能催化醇氧化，但萘氧基结合的铁(salan)配合物可以。
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