Tissue Engineering & Reparative Dentistry, School of Dentistry, Cardiff University, Heath Park, Cardiff CF14 4XY, UK.
Dent Mater. 2011 Oct;27(10):997-1002. doi: 10.1016/j.dental.2011.06.006. Epub 2011 Jul 23.
Polyacid-modified composite resins (compomers) are restorative dental materials that exhibit certain features of traditional dental composites and glass-ionomer cements. The aim of this paper was to develop experimental compomers with enhanced properties, based on adhesive monomers vinyl phosphonic acid and pyromellitic dianhydride glycerol dimethacrylate, and to compare their properties to those of commercially available products.
Factorial experimental design was employed to optimize both chemical and physical properties. Properties such as biaxial flexural strength (BFS), wear resistance (WR), water uptake (WU), and adhesion using shear bond strength (SBS) as well as fluoride release (FR) were evaluated and compared with those of commercial products.
Results were subjected to one-way ANOVA (p<0.05); significant differences were observed in properties of materials such as WR, BFS and SBS but not in WU and FR compared to commercial products. Experimental materials exhibited significantly higher WR, BFS and SBS values than commercial materials. Properties of materials were affected by their respective storage media with time.
Based on the results of this study, higher amounts of vinyl phosphonic acid (VPA), pyromellitic dianhydride glycerol dimethacrylate (PMGDM) and reactive glasses render the material with enhanced fluoride release and adhesion with properties similar to glass-ionomers whereas their decrease gives properties similar to conventional dental composite resins with improved properties such as strength and wear resistance.
聚酸改性复合树脂(复合体)是一种修复性牙科材料,具有传统牙科复合材料和玻璃离子水门汀的某些特性。本文旨在开发具有增强性能的实验性复合体,基于粘合单体乙烯基膦酸和均苯四甲酸二酐甘油二甲基丙烯酸酯,并将其性能与市售产品进行比较。
采用析因实验设计优化化学和物理性能。评估并比较了双轴弯曲强度(BFS)、耐磨性(WR)、吸水率(WU)和剪切结合强度(SBS)的粘合性能以及氟化物释放(FR)等性能,并与商业产品进行了比较。
结果进行了单因素方差分析(p<0.05);与商业产品相比,WR、BFS 和 SBS 等材料性能存在显著差异,但 WU 和 FR 无显著差异。实验材料的 WR、BFS 和 SBS 值明显高于商业材料。材料的性能随时间及其各自的储存介质而变化。
基于这项研究的结果,增加乙烯基膦酸(VPA)、均苯四甲酸二酐甘油二甲基丙烯酸酯(PMGDM)和反应性玻璃的含量会使材料具有增强的氟释放和粘合性能,类似于玻璃离子体,而减少这些成分则会使材料具有类似于传统牙科复合树脂的性能,具有增强的强度和耐磨性等性能。