Functional supramolecular assemblies derived from dendritic building blocks.

Control of the structure and function of self-assembled materials has been a significant issue in many areas of nanoscience. Among many different types of building blocks, dendritic ones have shown interesting self-assembly behaviour and functional performances due to their unique shape and multiple functionalities. Dendritic building blocks exhibit unique self-assembly behaviour in diverse environments such as aqueous and organic solutions, solid-liquid interfaces, and thermotropic solid conditions. Tuning the balance between hydrophilic and hydrophobic parts, as well as the external conditions for self-assembly, provides unique opportunities for control of supramolecular architectures. Furthermore, the introduction of suitable functional moieties into dendrons enables us to control self-assembly characteristics, allowing nanostructures to exhibit smart performances for electronic or biological applications. The self-assembly characteristics of amphiphilic dendrons under various conditions were investigated to elucidate how dendrons can assemble into nanoscopic structures and how these nanoassemblies exhibit unique properties. Well-defined nanostructures derived from self-assembly of dendrons provide an efficient approach for exhibition of unique functions at the nanoscale. This feature article describes the unique self-assembly characteristics of various types of dendritic building blocks and their potential applications as advanced materials.