School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.
Chem Soc Rev. 2012 Jan 21;41(2):666-86. doi: 10.1039/c1cs15078b. Epub 2011 Jul 28.
Graphene has attracted tremendous research interest in recent years, owing to its exceptional properties. The scaled-up and reliable production of graphene derivatives, such as graphene oxide (GO) and reduced graphene oxide (rGO), offers a wide range of possibilities to synthesize graphene-based functional materials for various applications. This critical review presents and discusses the current development of graphene-based composites. After introduction of the synthesis methods for graphene and its derivatives as well as their properties, we focus on the description of various methods to synthesize graphene-based composites, especially those with functional polymers and inorganic nanostructures. Particular emphasis is placed on strategies for the optimization of composite properties. Lastly, the advantages of graphene-based composites in applications such as the Li-ion batteries, supercapacitors, fuel cells, photovoltaic devices, photocatalysis, as well as Raman enhancement are described (279 references).
近年来,由于其独特的性质,石墨烯引起了极大的研究兴趣。大规模且可靠地生产石墨烯衍生物,如氧化石墨烯(GO)和还原氧化石墨烯(rGO),为合成各种应用的基于石墨烯的功能材料提供了广泛的可能性。这篇重要的综述介绍并讨论了基于石墨烯的复合材料的最新发展。在介绍了石墨烯及其衍生物的合成方法及其性质之后,我们重点描述了合成基于石墨烯的复合材料的各种方法,特别是那些具有功能性聚合物和无机纳米结构的复合材料。特别强调了优化复合材料性能的策略。最后,描述了基于石墨烯的复合材料在锂离子电池、超级电容器、燃料电池、光伏器件、光催化以及拉曼增强等应用中的优势(279 篇参考文献)。