高效金（I）催化的 Overman 重排反应在水中进行。
Highly efficient gold(I)-catalyzed Overman rearrangement in water.
机构信息
Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China.
出版信息
Beilstein J Org Chem. 2011;7:781-5. doi: 10.3762/bjoc.7.88. Epub 2011 Jun 8.
Abstract
A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yields.
摘要
报道了一种高效的金（I）催化的烯丙基三氯乙酰胺的 Overman 重排反应，在水中得到烯丙基三氯乙酰胺。采用这种环境友好且可规模化的方法，以良好至高产率合成了一系列 C3-取代的烯丙基三氯乙酰胺。
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