Adv Mater. 2011 Jun 17;23(22-23):2681-8. doi: 10.1002/adma.201100364.
Magneto-optical glasses are of considerable current interest, primarily for applications in fiber circuitry, optical isolation, all-optical diodes, optical switching and modulation. While the benchmark materials are still crystalline, glasses offer a variety of unique advantages, such as very high rare-earth and heavy-metal solubility and, in principle, the possibility of being produced in fiber form. In comparison to conventional fiber-drawing processes, pressure-assisted melt-filling of microcapillaries or photonic crystal fibers with magneto-optical glasses offers an alternative route to creating complex waveguide architectures from unusual combinations of glasses. For instance, strongly diamagnetic tellurite or chalcogenide glasses with high refractive index can be combined with silica in an all-solid, microstructured waveguide. This promises the implementation of as-yet-unsuitable but strongly active glass candidates as fiber waveguides, for example in photonic crystal fibers.
磁光玻璃目前受到了相当大的关注,主要应用于纤维电路、光学隔离、全光二极管、光开关和调制。虽然基准材料仍是晶体,但玻璃具有多种独特的优势,例如非常高的稀土和重金属溶解度,并且原则上可以制成纤维形式。与传统的纤维拉丝工艺相比,用磁光玻璃辅助加压填充微管或光子晶体光纤为从不同玻璃组合中制造复杂波导结构提供了另一种途径。例如,可以将强抗磁性碲酸盐或高折射率硫属化物玻璃与二氧化硅结合形成全固态微结构波导。这有望实现以前不适合但活性很强的玻璃候选材料作为光纤波导的应用,例如在光子晶体光纤中。