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以聚二甲基硅氧烷为中间体实现取向碳纳米管的通用转移

Versatile transfer of aligned carbon nanotubes with polydimethylsiloxane as the intermediate.

作者信息

Zhu Yanwu, Lim Xiaodai, Sim Mong Chea, Lim Chwee Teck, Sow Chorng Haur

机构信息

Department of Physics, Blk S12, Faculty of Science, National University of Singapore, 2 Science Drive 3, 117542, Singapore. National University of Singapore Nanoscience and Nanotechnology Initiative, Blk E3A, National University of Singapore, 9 Engineering Drive 1, 117576, Singapore.

出版信息

Nanotechnology. 2008 Aug 13;19(32):325304. doi: 10.1088/0957-4484/19/32/325304. Epub 2008 Jul 2.

Abstract

A simple technique to transfer aligned multi-walled carbon nanotubes (MWCNTs) is demonstrated in this work. With polydimethylsiloxane (PDMS) as the transfer medium, as-grown or patterned MWCNT arrays are directly transferred onto a wide variety of Pt-coated substrates such as glossy paper, cloth, polymers, glass slides, and metal foils at low temperatures. The surface of the transferred CNTs is cleaner with better alignment, compared with the as-grown one. Furthermore, the transferred CNTs show strong adhesion and good electric contact with the target substrates. A maximal current density of ∼10(4) A cm(-2) has been achieved from the CNT interconnects prepared with this technique. Because of the lower density and open-ended structures, improved field emission performance has been obtained from CNTs transferred on polymers, based on which flexible emitter devices can be fabricated. In addition, the surface of transferred CNTs becomes more hydrophilic, with an averaged contact angle of 93.4 ± 5.8°, in contrast to the super-hydrophobic as-grown CNT surface (contact angle 151.6 ± 5.5°). With versatile properties and flexible applications, the technique provides a simple and cost-effective way towards future nanodevices based on CNTs.

摘要

本文展示了一种转移排列好的多壁碳纳米管(MWCNTs)的简单技术。以聚二甲基硅氧烷(PDMS)作为转移介质,生长态或图案化的MWCNT阵列在低温下可直接转移到各种镀铂基底上,如光面纸、布料、聚合物、载玻片和金属箔。与生长态的碳纳米管相比,转移后的碳纳米管表面更清洁,排列更好。此外,转移后的碳纳米管与目标基底表现出很强的附着力和良好的电接触。用该技术制备的碳纳米管互连实现了约10(4) A cm(-2)的最大电流密度。由于密度较低且具有开口结构,转移到聚合物上的碳纳米管获得了改善的场发射性能,基于此可制造柔性发射器件。此外,转移后的碳纳米管表面变得更亲水,平均接触角为93.4±5.8°,而生长态的碳纳米管表面是超疏水的(接触角为151.6±5.5°)。该技术具有多种特性和灵活的应用,为未来基于碳纳米管的纳米器件提供了一种简单且经济高效的方法。

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