Li Hua-Qiong, Xian Hui-Duo, Liu Jian-Feng, Zhao Guo-Liang
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and, College of Chemistry and Life Science, Zhejiang Normal University, jinhua 321004, Zhejiang, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1495. doi: 10.1107/S1600536808035368.
The Schiff base 2-[(4-methyl-phen-yl)imino-meth-yl]-6-methoxy-phenol (HL) forms a complex with a Zn(2+) atom and two independent thio-cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thio-cyanate ligands. The coordination environment of the Zn atom is distorted-tetra-hedral.
席夫碱2-[(4-甲基-苯基)亚氨基甲基]-6-甲氧基苯酚（HL）与一个Zn(2+)原子和两个独立的硫氰酸根离子形成配合物[Zn(NCS)₂(C₁₅H₁₅NO₂)₂]，其中两个席夫碱配体的两个酚氧原子与Zn(2+)原子配位。质子化的亚胺氮原子与酚氧基形成分子内氢键。Zn原子还与两个硫氰酸根配体的两个氮原子配位。Zn原子的配位环境为扭曲四面体。
