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2,2'-[萘-1,5-二基双（次氮基甲亚基）]二苯酚

2,2'-[Naphthalene-1,5-diylbis(nitrilo-methanylyl-idene)]diphenol.

作者信息

Karthikeyan S, Muthukumaran J, Krishna R, Manimaran Bala

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1765-6. doi: 10.1107/S1600536811023099. Epub 2011 Jun 22.

DOI:10.1107/S1600536811023099
PMID:21837145
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3152037/
Abstract

The title compound, C(24)H(18)N(2)O(2), lies about an inversion centre and the asymmetric unit contains one half-mol-ecule. An intra-molecular O-H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. The crystal packing exhibits inter-molecular π-π stacking inter-actions between the aromatic rings with a centroid-centroid distance of 3.851 (2) Å.

摘要

标题化合物C(24)H(18)N(2)O(2)位于一个对称中心上，不对称单元包含半个分子。分子内的O—H⋯N氢键形成一个六元环，产生S(6)环模式。晶体堆积显示芳环之间存在分子间π-π堆积相互作用，质心间距为3.851 (2) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/00702eb56602/e-67-o1765-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/349fed8907b8/e-67-o1765-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/c30bcbe8acc7/e-67-o1765-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/00702eb56602/e-67-o1765-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/349fed8907b8/e-67-o1765-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/c30bcbe8acc7/e-67-o1765-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83d9/3152037/00702eb56602/e-67-o1765-fig3.jpg

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