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比较 ICP-OES 法测定几种干果果样中多种元素时的干法、湿法和微波消解。

Comparison of dry, wet and microwave digestion methods for the multi element determination in some dried fruit samples by ICP-OES.

机构信息

Sakarya University, Faculty of Science and Arts, Chemistry Department, 54187 Sakarya, Turkey.

出版信息

Food Chem Toxicol. 2011 Nov;49(11):2800-7. doi: 10.1016/j.fct.2011.07.064. Epub 2011 Aug 6.

Abstract

The aim of this study was used to investigate the level of trace metals (Ba, Pb, Cd, Mn, Cr, Co, Ni, Cu, Mn, Zn, Sr and Fe) in some dried fruits (Prunus domestica L., Ficus carica L., Morus alba L., Vitis vinifera L., Prunus armeniaca L., and Malus domestica) samples from Turkey. Trace elements were determined by ICP-OES after dry, wet and microwave digestion methods in dried fruit samples. Validation of the proposed method was carried out by using a NIST-SRM 1515-Apple Leaves certified reference material. Element concentrations in dried fruit samples were 0.33-1.77 (Ba), 0.12-0.54 (Cd), 0.25-1.03 (Co), 0.45-2.30 (Cr), 0.43-2.74 (Cu), 0.56-4.87 (Mn), 0.61-2.54 (Ni), 0.40-2.14 (Pb), 2.16-6.54 (Zn), 0.83-12.02 (Al), 11.82-40.80 (Fe) and 0.16-6.34 (Sr) μg/g. The analytical parameters show that the microwave oven digestion procedure provided best results as compared to the wet and dry digestion procedures. The results were compared with the literature values.

摘要

本研究旨在测定土耳其部分干果果脯(桃、无花果、桑椹、葡萄、杏和苹果)中痕量金属(钡、铅、镉、锰、铬、钴、镍、铜、锌、锶和铁)的水平。采用干、湿和微波消解法对干果果脯样品中的微量元素进行测定,并用 ICP-OES 进行分析。通过使用 NIST-SRM 1515-Apple Leaves 标准参考物质对所提出的方法进行验证。干果果脯样品中的元素浓度为 0.33-1.77(钡)、0.12-0.54(镉)、0.25-1.03(钴)、0.45-2.30(铬)、0.43-2.74(铜)、0.56-4.87(锰)、0.61-2.54(镍)、0.40-2.14(铅)、2.16-6.54(锌)、0.83-12.02(铝)、11.82-40.80(铁)和 0.16-6.34(锶)μg/g。分析参数表明,与湿消解和干消解相比,微波消解程序提供了最佳结果。研究结果与文献值进行了比较。

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