具有外围吡咯并[2,3-f]喹喔啉的卟啉-树枝状分子的合成及其立方非线性光学性质。
Synthesis of porphyrin-dendrimers with a pyrene in the periphery and their cubic nonlinear optical properties.
机构信息
Instituto de Química, Universidad Nacional Autónoma de México, Cd. Universitaria, Circuito Exterior, Coyoacán, CP, México DF 04510, Mexico.
出版信息
Molecules. 2011 Aug 15;16(8):6950-68. doi: 10.3390/molecules16086950.
Dendrons of pyrene derivatives were attached to a porphyrin core. A marked effect in solution for the dendrimers was observed in the absorption spectra. All the compounds obtained were characterized by (1)H-, (13)C-NMR, FTIR, UV-vis, MALDI-TOF or FAB+ mass spectrometry and elemental analysis. The cubic nonlinear optical behavior of some the synthesized compounds was tested via Z-Scan measurements in spin-coated film samples.
将芘衍生物的树枝状分子连接到卟啉核心上。在吸收光谱中观察到树枝状聚合物在溶液中表现出显著的影响。所有得到的化合物都通过（1）H-NMR、（13）C-NMR、FTIR、UV-vis、MALDI-TOF 或 FAB+质谱和元素分析进行了表征。通过旋涂薄膜样品的 Z-扫描测量测试了一些合成化合物的立方非线性光学行为。
Zotero 插件