一种具有24个[Fe(η⁵-C₅Me₅)(η¹-N-烷基苯胺)]末端基团的聚阳离子金属树枝状大分子，可识别氯离子和溴离子阴离子。
A Polycationic Metallodendrimer with 24 [Fe(η -C Me )(η -N-Alkylaniline)] Termini That Recognizes Chloride and Bromide Anions.
作者信息
Valério Christine, Alonso Ester, Ruiz Jaime, Blais Jean-Claude, Astruc Didier
机构信息
Groupe de Chimie Supramoléculaire des Métaux de Transition, Laboratoire de Chimie Organique et Organométallique (LCOO), UMR CNRS No. 5802, Université Bordeaux I, 351, Cours de la Libération, F-33405 Talence Cédex (France), Fax: (+33) 5-56-84-66-46.
Laboratoire de Chimie Structurale Organique et Biologique, Université Paris VI (France).
出版信息
Angew Chem Int Ed Engl. 1999 Jun 14;38(12):1747-1751. doi: 10.1002/(SICI)1521-3773(19990614)38:12<1747::AID-ANIE1747>3.0.CO;2-G.
Pronounced dendritic effects are shown by the title compound 1 in the recognition of Cl and Br -this is shown by the comparison with a mononuclear compound with one dendrimer arm and a trinuclear compound with a tripodal dendrimer branch. Thus, 1 differs distinctly from 24-ferrocene dendrimers of comparable topology.
标题化合物1在识别氯离子和溴离子时表现出明显的树枝状效应——这通过与具有一个树枝状聚合物臂的单核化合物以及具有三脚架状树枝状聚合物分支的三核化合物进行比较得以体现。因此，1与拓扑结构相当的24-二茂铁树枝状聚合物明显不同。
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