用于钯的比色和比率荧光探针。
A colorimetric and ratiometric fluorescent probe for palladium.
机构信息
Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, PR China.
出版信息
Org Lett. 2011 Sep 16;13(18):4922-5. doi: 10.1021/ol202003j. Epub 2011 Aug 24.
A colorimetric and ratiometric fluorescent probe for the palladium species has been developed based on the Pd(0)-catalyzed cleavage of an allyoxycarbonyl group of amines under mild conditions. The probe displays a highly sensitive and selective response with significant changes in both color (from colorless to jade-green) and fluorescence (from blue to green), through the ICT process.
一种基于钯（0）催化条件下温和裂解胺的烯丙氧基羰基的比色和比率型荧光探针已被开发。该探针通过 ICT 过程，表现出对钯物种高灵敏和选择性响应，其颜色（从无色变为玉绿色）和荧光（从蓝色变为绿色）均发生显著变化。
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