非血红素 Ni(II)(O2)配合物的氧化性质：C-H 活化、芳环羟化和杂原子氧化的反应模式。
Oxidative properties of a nonheme Ni(II)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation.
机构信息
Manchester Interdisciplinary Biocenter and School of Chemical Engineering and Analytical Science, University of Manchester, 131 Princess Street, Manchester M1 7DN, UK.
出版信息
Chem Commun (Camb). 2011 Oct 14;47(38):10674-6. doi: 10.1039/c1cc13993b. Epub 2011 Sep 2.
PMID:21892444
Abstract
Density functional theory calculations on the reactivity of a Ni(II)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(II)-superoxo complex is able to react with substrates with weak C-H bonds and PPh(3).
摘要
密度泛函理论计算研究了 Ni(II)-过氧配合物在 C-H 键活化、芳基羟化和杂原子氧化反应中的反应性；Ni(II)-过氧配合物能够与弱 C-H 键和 PPh(3)的底物反应。
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