Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Rd, Shanghai, 200237, China.
Chem Commun (Camb). 2011 Oct 14;47(38):10707-9. doi: 10.1039/c1cc14169d. Epub 2011 Sep 5.
Embedding Pd nanoparticles in carbon thin film-lined SBA-15 nanoreactors provides highly efficient catalysts for heterogeneous cross coupling reactions in aqueous media. No leaching or aggregation of Pd nanoparticles was found in these nanoreactors after reusing them several times. The carbon thin film lining of these nanoreactors was further confirmed with small molecular arene probing experiments.
将 Pd 纳米颗粒嵌入到带有碳薄膜内衬的 SBA-15 介孔纳米反应器中，为水相多相交叉偶联反应提供了高效的催化剂。在多次重复使用后，这些纳米反应器中的 Pd 纳米颗粒没有浸出或聚集。通过小分子芳烃探针实验进一步证实了这些纳米反应器的碳薄膜内衬。
