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Iron-catalyzed coupling of aryl Grignard reagents with alkyl halides: a competitive Hammett study.

作者信息

Hedström Anna, Bollmann Ulla, Bravidor Jenny, Norrby Per-Ola

机构信息

Department of Chemistry, University of Gothenburg, Kemigården 4, 412-96, Gothenburg, Sweden.

出版信息

Chemistry. 2011 Oct 17;17(43):11991-3. doi: 10.1002/chem.201100467. Epub 2011 Sep 16.

DOI:10.1002/chem.201100467
PMID:21922569
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3229983/
Abstract
摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/9520b0fe32b7/chem0017-11991-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/ae66c922f7d0/chem0017-11991-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/cb81076d1055/chem0017-11991-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/6848b338ffb1/chem0017-11991-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/9520b0fe32b7/chem0017-11991-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/ae66c922f7d0/chem0017-11991-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/cb81076d1055/chem0017-11991-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/6848b338ffb1/chem0017-11991-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f12/3229983/9520b0fe32b7/chem0017-11991-f4.jpg

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本文引用的文献

1
Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions.计算探索铜催化的乌尔曼型反应的机制和配体导向选择性。
J Am Chem Soc. 2010 May 5;132(17):6205-13. doi: 10.1021/ja100739h.
2
Structure-reactivity relationships in negishi cross-coupling reactions.Negishi 交叉偶联反应中的结构-反应性关系。
Chemistry. 2010 Jan 4;16(1):248-53. doi: 10.1002/chem.200902132.
3
Iron-catalyzed cross-coupling of alkyl halides with alkenyl grignard reagents.铁催化卤代烃与烯基格氏试剂的交叉偶联反应。
Angew Chem Int Ed Engl. 2020 Jul 13;59(29):11866-11870. doi: 10.1002/anie.202004090. Epub 2020 May 14.
4
Multinuclear iron-phenyl species in reactions of simple iron salts with PhMgBr: identification of Fe(μ-Ph)(THF) as a key reactive species for cross-coupling catalysis.简单铁盐与苯基溴化镁反应中的多核铁-苯基物种：鉴定Fe(μ-Ph)(THF)为交叉偶联催化的关键活性物种。
Chem Sci. 2018 Aug 24;9(41):7931-7939. doi: 10.1039/c8sc02915f. eCollection 2018 Nov 7.
Angew Chem Int Ed Engl. 2007;46(34):6521-4. doi: 10.1002/anie.200702206.
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Iron-catalyzed alkylations of aromatic grignard reagents.铁催化的芳基格氏试剂的烷基化反应。
Angew Chem Int Ed Engl. 2007;46(23):4364-6. doi: 10.1002/anie.200700742.
5
Iron-phosphine, -phosphite, -arsine, and -carbene catalysts for the coupling of primary and secondary alkyl halides with aryl Grignard reagents.用于伯卤代烃和仲卤代烃与芳基格氏试剂偶联反应的铁-膦、铁-亚膦酸酯、铁-胂和铁-卡宾催化剂。
J Org Chem. 2006 Feb 3;71(3):1104-10. doi: 10.1021/jo052250+.
6
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