叠氮化甲基钌：一种有用的茂金属衍生物的简便合成及其在生物分子的“点击”标记中的应用。
Azidomethyl-ruthenocene: facile synthesis of a useful metallocene derivative and its application in the 'click' labelling of biomolecules.
机构信息
Lehrstuhl für Anorganische Chemie I, Bioanorganische Chemie, Fakultät für Chemie und Biochemie, Ruhr-Universität Bochum, Universitätsstr. 150, 44801, Bochum, Germany.
出版信息
Chem Commun (Camb). 2011 Nov 7;47(41):11444-6. doi: 10.1039/c1cc14537a. Epub 2011 Sep 21.
PMID:21935541
Abstract
A convenient synthesis of azidomethyl-ruthenocene and its use in the covalent labelling of amino acids, peptides and a peptide nucleic acid (PNA) monomer derivative by Cu(I) catalyzed azide-alkyne coupling (Cu-AAC, "click chemistry") are described.
摘要
方便地合成叠氮甲基-钌并将其用于通过 Cu(I) 催化的叠氮-炔烃偶联 (Cu-AAC，“点击化学”) 对氨基酸、肽和肽核酸 (PNA) 单体衍生物进行共价标记。
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