通过钛亚氮基得到一个四配位的双亲酰亚胺。
A four coordinate parent imide via a titanium nitridyl.
机构信息
Indiana University, 800 E. Kirkwood Avenue, Bloomington, Indiana, USA.
出版信息
Chem Commun (Camb). 2012 Feb 1;48(10):1529-31. doi: 10.1039/c1cc14574f. Epub 2011 Oct 5.
PMID:21971561
Abstract
Treatment of d(1) [(nacnac)TiCl(Ntol(2))] with NaN(3) results in NaCl formation and N(2) ejection to yield the first four coordinate, parent imide [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=ArNC(CH(3))CH, Ar = 2,6-iPr(2)C(6)H(3), tol = 4-CH(3)C(6)H(4)).
摘要
用 NaN(3) 处理 d(1) [(nacnac)TiCl(Ntol(2))] 会导致生成 NaCl 和 N(2) 逸出，从而得到第一个四配位、母体酰亚胺 [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=ArNC(CH(3))CH，Ar = 2,6-iPr(2)C(6)H(3)，tol = 4-CH(3)C(6)H(4))。
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