A Mononuclear and High-Spin Tetrahedral Ti Complex.

A high-spin, mononuclear Ti complex, [(Tp)TiCl] [Tp = hydridotris(3--butyl-5-methylpyrazol-1-yl)borate], confined to a tetrahedral ligand-field environment, has been prepared by reduction of the precursor [(Tp)TiCl] with KC. Complex [(Tp)TiCl] has a A ground state (assuming symmetry based on structural studies), established a combination of high-frequency and -field electron paramagnetic resonance (HFEPR) spectroscopy, solution and solid-state magnetic studies, Ti K-edge X-ray absorption spectroscopy (XAS), and both density functional theory and ab initio (complete-active-space self-consistent-field, CASSCF) calculations. The formally and physically defined Ti complex readily binds tetrahydrofuran (THF) to form the paramagnetic adduct [(Tp)TiCl(THF)], which is impervious to N binding. However, in the absence of THF, the Ti complex captures N to produce the diamagnetic complex (Tp)TiCl, with a linear Ti═N═N═Ti topology, established by single-crystal X-ray diffraction. The N complex was characterized using XAS as well as IR and Raman spectroscopies, thus establishing this complex to possess two Ti centers covalently bridged by an N unit. A π acid such as CNAd (Ad = 1-adamantyl) coordinates to [(Tp)TiCl] without inducing spin pairing of the d electrons, thereby forming a unique high-spin and five-coordinate Ti complex, namely, [(Tp)TiCl(CNAd)]. The reducing power of the coordinatively unsaturated Ti-containing [(Τp)TiCl] species, quantified by electrochemistry, provides access to a family of mononuclear Ti complexes of the type [(Tp)Ti═E(Cl)] (with E = NSiMe, NCPh, O, and NH) by virtue of atom- or group-transfer reactions using various small molecules such as NSiMe, NCPh, NO, and the bicyclic amine 2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene.