一种使用修饰有氢化酶和黄递酶部分的石墨颗粒再生 NAD 辅因子的模块化系统。
A modular system for regeneration of NAD cofactors using graphite particles modified with hydrogenase and diaphorase moieties.
机构信息
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
出版信息
Chem Commun (Camb). 2012 Feb 1;48(10):1589-91. doi: 10.1039/c1cc14826e. Epub 2011 Oct 10.
PMID:21986817
Abstract
Pyrolytic graphite particles modified with hydrogenase and an NAD(+)/NADH cycling enzyme provide a modular heterogeneous catalyst system for regeneration of oxidised or reduced nicotinamide cofactors using H(2) and H(+) as electron source or sink. Particles can be tuned for cofactor supply under different conditions by appropriate choice of hydrogenase.
摘要
经氢化酶和 NAD(+) / NADH 循环酶修饰的热解石墨颗粒为使用 H(2) 和 H(+) 作为电子源或汇来再生氧化或还原烟酰胺辅酶提供了一种模块化的多相催化剂体系。通过选择合适的氢化酶，可以根据不同的条件调整颗粒来提供辅酶。
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