在 Cu(111)表面上直接金属化四(4-溴苯基)卟啉时形成中间体络合物的证据。
Evidence for the formation of an intermediate complex in the direct metalation of tetra(4-bromophenyl)-porphyrin on the Cu(111) surface.
机构信息
School of Physical Sciences, Dublin City University, Dublin 9, Ireland.
出版信息
Chem Commun (Camb). 2011 Nov 28;47(44):12134-6. doi: 10.1039/c1cc15241f. Epub 2011 Oct 13.
PMID:21993371
Abstract
A strong molecule-surface interaction between free-base-tetra(4-bromophenyl)-porphyrin and Cu(111) results in a distortion of both the molecule and the underlying copper surface in the vicinity of the molecule. This in turn leads to the formation of an intermediate complex due to bonding between the iminic nitrogens and surface copper atoms.
摘要
自由碱四（4-溴苯基）卟啉与 Cu(111) 之间存在强烈的分子-表面相互作用，导致分子和底层铜表面在分子附近发生扭曲。这反过来又导致亚氨基氮和表面铜原子之间的键合形成中间配合物。
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