Cohen Samuel I A, Vendruscolo Michele, Dobson Christopher M, Knowles Tuomas P J
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
Int J Mol Sci. 2011;12(9):5844-52. doi: 10.3390/ijms12095844. Epub 2011 Sep 9.
We revisit the classical problem of nucleated polymerisation and derive a range of exact results describing polymerisation in systems intermediate between the well-known limiting cases of a reaction starting from purely soluble material and for a reaction where no new growth nuclei are formed.
我们重新审视了成核聚合的经典问题,并得出了一系列精确结果,这些结果描述了在介于从纯可溶材料开始反应的著名极限情况和不形成新生长核的反应之间的系统中的聚合过程。