Dpto. Química Orgánica, Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza, C.S.I.C., 50009-Zaragoza, Spain.
Angew Chem Int Ed Engl. 2011 Dec 23;50(52):12523-8. doi: 10.1002/anie.201104866. Epub 2011 Nov 4.
What a core-ker! By the appropriate combination of promesogenic bent-core structures and the C(60) unit, lamellar polar liquid-crystal phases were induced. The supramolecular organization of the functional fullerene-based assemblies, the temperature range of the soft phase, the stabilization of the mesophase-like order at room temperature, and the molecular switching under an electric field can be tuned, depending on the molecular structure.
真是太棒了！通过将准晶向列型双锥结构和 C(60)单元进行适当组合，诱导出了层状极性液晶相。基于功能富勒烯组装体的超分子组织、软相的温度范围、室温下类似介相有序的稳定以及电场下的分子开关，可以根据分子结构进行调节。
