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四水双[3-(吡啶-4-基)苯甲酸根-κN]钴(II)

Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-κN]cobalt(II).

作者信息

Wang Hai-Rong, Li Guo-Ting

机构信息

Department of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1743. doi: 10.1107/S1600536811046496. Epub 2011 Nov 12.

DOI:10.1107/S1600536811046496
PMID:22199542
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238651/
Abstract

In the title compound, [Co(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Co atom lies on a twofold rotation axis and has an N(2)O(4) octa-hedral coordination environment formed by four O atoms of water mol-ecules in the equatorial plane and two apical N atoms of pyridine groups. An intricate three-dimensional supra-molecular network is formed by multiple O-H⋯O hydrogen bonds between the coordinated water mol-ecules and the uncoordinated carboxyl-ate groups.

摘要

在标题化合物[Co(C₁₂H₈NO₂)₂(H₂O)₄]中，Co原子位于一个二重旋转轴上，具有由赤道平面上四个水分子的O原子和两个吡啶基团的顶端N原子形成的N₂O₄八面体配位环境。配位水分子与未配位羧酸根基团之间通过多个O—H⋯O氢键形成了一个复杂的三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a1a/3238651/69903681ae02/e-67-m1743-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a1a/3238651/6a0a31e868b1/e-67-m1743-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a1a/3238651/69903681ae02/e-67-m1743-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a1a/3238651/6a0a31e868b1/e-67-m1743-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a1a/3238651/69903681ae02/e-67-m1743-fig2.jpg

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1
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Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand.一种新型螺旋双层钴（II）-有机框架，其具有由不对称吡啶基苯甲酸酯配体连接的四核[Co4(μ3-OH)2]簇。
Inorg Chem. 2007 Oct 29;46(22):9021-3. doi: 10.1021/ic701003z. Epub 2007 Sep 22.
3
New lanthanide hybrid as clustered infinite nanotunnel with 3D Ln-O-Ln framework and (3,4)-connected net.
新型镧系杂化物，具有三维Ln-O-Ln框架和(3,4)连接网络的簇状无限纳米隧道。
Inorg Chem. 2007 Feb 19;46(4):1171-6. doi: 10.1021/ic0615271.
4
Functional supramolecular devices: [M4IIL4]8+ [2 x 2]-grid-type complexes as multilevel molecular electronic species.
Chemistry. 2003 Jan 3;9(1):291-9. doi: 10.1002/chem.200390022.