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Tetra-aqua-bis-(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetato)-cobalt(II) monohydrate.

作者信息

Yang Guang-Rui, Li Guo-Ting

机构信息

Department of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1746-7. doi: 10.1107/S1600536811046526. Epub 2011 Nov 12.

DOI:10.1107/S1600536811046526
PMID:22199545
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238654/
Abstract

In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxyl-ate O atom. The Co(II) atom adopts a slightly distorted octa-hedral coordination geometry with four O atoms of the coordinated water mol-ecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions. In the crystal, the components are connected through O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensional framework.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/616a/3238654/41eafe8b9a7e/e-67-m1746-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/616a/3238654/a52499343385/e-67-m1746-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/616a/3238654/41eafe8b9a7e/e-67-m1746-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/616a/3238654/a52499343385/e-67-m1746-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/616a/3238654/41eafe8b9a7e/e-67-m1746-fig2.jpg

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本文引用的文献

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Modulated preparation and structural diversification of ZnII and CdII metal-organic frameworks with a versatile building block 5-(4-pyridyl)-1,3,4-oxadiazole-2-thiol.基于多功能构筑块5-(4-吡啶基)-1,3,4-恶二唑-2-硫醇的锌（II）和镉（II）金属有机框架的调制制备及结构多样化
Inorg Chem. 2006 Jul 24;45(15):5785-92. doi: 10.1021/ic060129v.