Li Yu-Xian, Li Da-Wei, Zhao Dong
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1251. doi: 10.1107/S1600536811032442. Epub 2011 Aug 17.
In the title complex, [Cd(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Cd(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand and by five O atoms from four water mol-ecules and one monodentate sulfate anion in a distorted octa-hedral geometry. The sulfate tetra-hedron is rotationally disordered over two positions in a 0.651 (12):0.349 (12) ratio. In the crystal, adjacent mol-ecules are linked through O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensional network.
在标题配合物[Cd(SO₄)(C₉H₈N₆)(H₂O)₄]·2H₂O中,Cd(II)离子由来自1-[(1H-1,2,3-苯并三唑-1-基)甲基]-1H-1,2,4-三唑配体的一个N原子以及来自四个水分子和一个单齿硫酸根阴离子的五个O原子以扭曲的八面体几何构型六配位。硫酸根四面体在两个位置上以0.651(12):0.349(12)的比例旋转无序。在晶体中,相邻分子通过O-H⋯O和O-H⋯N氢键连接成三维网络。