Li Yu-Xian, Li Da-Wei, Zhao Dong
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1078. doi: 10.1107/S1600536811027231. Epub 2011 Jul 13.
In the title complex, [Co(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Co(II) ion is six-coordinated by one N atom from a 1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand, one O atom from a monodentate sulfate ligand and four water mol-ecules in a slightly distorted octa-hedral geometry. The sulfate ligand is rotationally disordered over two sets of sites with refined occupancies of 0.662 (15) and 0.338 (15). In the crystal, complex mol-ecules and solvent water mol-ecules are linked through inter-molecular O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensional network.
在标题配合物[Co(SO₄)(C₉H₈N₆)(H₂O)₄]·2H₂O中，Co(II)离子由1H-1,2,3-苯并三唑-1-基)甲基]-1H-1,2,4-三唑配体中的一个N原子、单齿硫酸根配体中的一个O原子以及四个水分子以稍微扭曲的八面体几何构型进行六配位。硫酸根配体在两组位置上呈旋转无序，精制占有率分别为0.662 (15)和0.338 (15)。在晶体中，配合物分子和溶剂水分子通过分子间的O-H⋯O和O-H⋯N氢键连接成三维网络。
