二水合{2-(4-羟基苯基)-2-[(3-甲氧基-2-氧化苄基亚甲基)氨基-κO,N]丙酸根-κO}(1,10-菲咯啉-κN,N')铜(II)
{2-(4-Hy-droxy-phen-yl)-2-[(3-meth-oxy-2-oxidobenzyl-idene)amino-κO,N]propanoato-κO}(1,10-phenanthroline-κN,N')copper(II) dihydrate.
作者信息
Pu Xuewei, Li Lianzhi, Dong Jianfang, Jing Buqin
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m465-6. doi: 10.1107/S1600536811009627. Epub 2011 Mar 19.
Abstract
In the title complex, [Cu(C(17)H(15)NO(5))(C(12)H(8)N(2))]·2H(2)O, the central Cu(II) ion is five-coordinate, bound to one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal configuration. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds form a two-dimensional network parallel to (001).
摘要
在标题配合物[Cu(C₁₇H₁₅NO₅)(C₁₂H₈N₂)]·2H₂O中，中心Cu(II)离子为五配位，通过一个席夫碱配体的一个N原子和两个O原子以及一个1,10 - 菲咯啉配体的两个N原子以扭曲的四方锥构型配位。在晶体中，分子间的O—H⋯O和C—H⋯O氢键形成了平行于(001)的二维网络。
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