Messai Amel, Benali-Cherif Rim, Jeanneau Erwann, Benali-Cherif Nourredine
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1204. doi: 10.1107/S1600536811031072. Epub 2011 Aug 6.
In the title complex, [Ni(C(5)H(9)NO(2))(2)(H(2)O)(2)], the Ni(II) atom, located on a centre of inversion, is trans-coordinated by two O atoms and two N atoms from d-bidentate valine and l-bidentate valine ligands and two water O atoms in an octa-hedral geometry. In the crystal, the discrete mononuclear units are linked into a three-dimensional network via O-H⋯O and N-H⋯O hydrogen bonds. C-H⋯O inter-actions are also observed.
在标题配合物[Ni(C₅H₉NO₂)₂(H₂O)₂]中,位于对称中心的Ni(II)原子通过来自d-双齿缬氨酸和l-双齿缬氨酸配体的两个O原子、两个N原子以及两个水分子的O原子以八面体几何构型进行反式配位。在晶体中,离散的单核单元通过O—H⋯O和N—H⋯O氢键连接成三维网络。还观察到了C—H⋯O相互作用。