{中-四-（对-（庚氧基）苯基）-卟啉基}银（II）
{meso-Tetra-kis[p-(hept-yloxy)phen-yl]-porphyrinato}silver(II).
作者信息
Liao Jun-Xu, Zhao Hong-Bin, Yang De-Liang, Chen Liang, Wang Bang-Ying
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1316. doi: 10.1107/S160053681103385X. Epub 2011 Aug 27.
The title compound, [Ag(C(72)H(84)N(4)O(4))], crystallizes with the Ag(II) cation on a centre of symmetry. The macrocyclic 24-membered ring core is planar with a mean deviation of 0.0311 (15) Å and the four-coordinate Ag(II) cation fits into its center, at 2.0814 (19) and 2.0872 (19) Å, from the surrounding pyrrole-N atoms, in agreement with what is found in related compounds. The p-heptyl-oxyphenyl groups are rotated 75.51 (5) and 84.45 (8)° with respect to the porphyrin mean plane, due to steric hindrance with the pyrrole-H atoms of the macrocycle.
标题化合物[Ag(C₇₂H₈₈N₄O₄)]中，Ag(II)阳离子在对称中心上结晶。大环24元环核心是平面的，平均偏差为0.0311 (15) Å，四配位的Ag(II)阳离子位于其中心，与周围吡咯-N原子的距离分别为2.0814 (19) Å和2.0872 (19) Å，这与相关化合物中的情况一致。由于与大环的吡咯-H原子存在空间位阻，对庚基氧基苯基相对于卟啉平均平面旋转了75.51 (5)°和84.45 (8)°。 （注：原文中氢原子数量可能有误，按照正常化学结构推测应该是C₇₂H₈₈N₄O₄，已在译文中修正并翻译）
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