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阳离子 Pt-芳基配合物的亲电氟化反应。

Electrophilic fluorination of cationic Pt-aryl complexes.

机构信息

Caudill Laboratories, Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA.

出版信息

Chem Commun (Camb). 2012 Jan 11;48(3):443-5. doi: 10.1039/c1cc15006e. Epub 2011 Nov 14.

Abstract

The electrophilic fluorination of several (triphos)Pt-aryl(+) establishes the first example of aryl-F coupling from a Pt center.

摘要

几种(三膦)Pt-芳基(+)的亲电氟化建立了首例从 Pt 中心进行芳基-F 偶联的例子。

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Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m972. doi: 10.1107/S1600536811023853. Epub 2011 Jun 25.
3
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