State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China.
Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8176-9. doi: 10.1002/anie.201103225. Epub 2011 Jul 14.
A nice combination: the intramolecular oxidative aminofluorination of allenes using silver catalysis and FN(SO(2)Ph)(2) as the fluorinating reagent has been developed. This reaction represents an efficient method for the synthesis of various 4-fluoro-2,5-dihydropyrrole compounds. Further transformation provided the corresponding fluorinated pyrrole derivatives in good yields.
使用银催化和 FN(SO(2)Ph)(2)作为氟源，实现了丙二烯的分子内氧化氨氟化反应。该反应为合成各种 4-氟-2,5-二氢吡咯化合物提供了一种有效的方法。进一步的转化以良好的收率得到了相应的氟化吡咯衍生物。
