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[双（3-氨基丙基）胺-κN，N'，N'']双（硫氰酸根合-κN）钴（II）

[Bis(3-amino-prop-yl)amine-κN,N',N'']bis-(thio-cyanato-κN)cobalt(II).

作者信息

Boeckmann Jan, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1025-6. doi: 10.1107/S1600536811025876. Epub 2011 Jul 6.

DOI:10.1107/S1600536811025876
PMID:22090820
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212118/
Abstract

The asymmetric unit of the title compound, [Co(NCS)(2)(C(6)H(17)N(3))], consists of one Co(2+) cation, two thio-cyanate anions and one bis-(3-amino-prop-yl)amine ligand, all in general positions. The cobalt cation is coordinated by five N atoms of two terminal N-bonded thio-cyanate anions and one bis-(3-amino-prop-yl)amine ligand, defining a slightly distorted square-pyramidal coordination polyhedron. The mol-ecules are held together in the crystal by weak N-H⋯S inter-actions.

摘要

标题化合物[Co(NCS)₂(C₆H₁₇N₃)]的不对称单元由一个Co²⁺阳离子、两个硫氰酸根阴离子和一个双(3-氨基丙基)胺配体组成，它们均处于一般位置。钴阳离子由两个末端N键合硫氰酸根阴离子的五个N原子和一个双(3-氨基丙基)胺配体配位，形成一个略微扭曲的四方锥配位多面体。分子通过弱的N-H⋯S相互作用在晶体中聚集在一起。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6efd/3212118/d9a26c0ecd2c/e-67-m1025-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6efd/3212118/d71560d25994/e-67-m1025-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6efd/3212118/d9a26c0ecd2c/e-67-m1025-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6efd/3212118/d71560d25994/e-67-m1025-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6efd/3212118/d9a26c0ecd2c/e-67-m1025-fig2.jpg

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2
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Chem Commun (Camb). 2011 Jul 7;47(25):7104-6. doi: 10.1039/c1cc12273h. Epub 2011 May 27.
3
Solid-state transformation of [Co(NCS)2(pyridine)4] into [Co(NCS)2(pyridine)2]n: from Curie-Weiss paramagnetism to single chain magnetic behaviour.[Co(NCS)2(pyridine)4]到[Co(NCS)2(pyridine)2]n的固态相变：从居里-外斯顺磁体到单链磁体行为。
Dalton Trans. 2010 Dec 7;39(45):11019-26. doi: 10.1039/c0dt00904k. Epub 2010 Oct 14.
4
Rational design of bridging selenocyanates by thermal decomposition reactions.通过热分解反应合理设计桥连硒氰酸盐。
Chem Commun (Camb). 2010 Jul 14;46(26):4707-9. doi: 10.1039/c0cc00064g.
5
Thermal decomposition reactions as tool for the synthesis of new metal thiocyanate diazine coordination polymers with cooperative magnetic phenomena.热分解反应作为一种新的金属硫氰酸根二嗪配位聚合物的合成工具，具有协同磁现象。
Inorg Chem. 2009 Jul 20;48(14):6896-903. doi: 10.1021/ic9002498.
6
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Dalton Trans. 2009 Oct 14(38):7975-84. doi: 10.1039/b907645j. Epub 2009 Aug 12.
7
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.