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链状聚[[二碘镉]-μ-[4,4'-(2,3,5,6-四甲基-1,4-亚苯基)双-(亚甲基)]双-(3,5-二甲基-1H-吡唑)-κN:N]

catena-Poly[[diiodidocadmium]-μ-[4,4'-(2,3,5,6-tetra-methyl-1,4-phenyl-ene)bis-(methyl-ene)]bis-(3,5-dimethyl-1H-pyrazole)-κN:N].

作者信息

Zhou Yuanyuan, Wang Zhaoyang, Yang Guang, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1037. doi: 10.1107/S1600536811025797. Epub 2011 Jul 6.

DOI:10.1107/S1600536811025797
PMID:22090830
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212128/
Abstract

The heterocylic ligand of the polymeric title compound, [CdI(2)(C(22)H(30)N(4))], links two adjacent CdI(2) units, forming a chain running parallel to [[Formula: see text]01]. The Cd(II) atom is located on a twofold rotation axis and shows a distorted tetra-hedral CdI(2)N(2) coordination. The mid-point of the benzene ring of the ligand lies on a center of inversion. There are no classical hydrogen-bonding inter-actions present.

摘要

标题聚合物化合物[CdI₂(C₂₂H₃₀N₄)]的杂环配体连接两个相邻的CdI₂单元，形成一条平行于[化学式：见正文]01的链。Cd(II)原子位于二重旋转轴上，呈现出扭曲的四面体CdI₂N₂配位结构。配体苯环的中点位于对称中心上。不存在经典的氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a71f/3212128/d323c04c41dc/e-67-m1037-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a71f/3212128/d323c04c41dc/e-67-m1037-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a71f/3212128/d323c04c41dc/e-67-m1037-fig1.jpg

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本文引用的文献

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