（2,9-二甲基-1,10-菲咯啉-κN,N'）二碘镉
(2,9-Dimethyl-1,10-phenanthroline-κN,N')diiodidocadmium.
作者信息
Warad Ismail, Boshaala Ahmed, Al-Resayes Saud I, Al-Deyab Salem S, Rzaigui Mohamed
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1650. doi: 10.1107/S1600536811044667. Epub 2011 Nov 2.
In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol-ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra-hedral geometry. Inversion-related mol-ecules inter-act along the c-axis direction by π-π stacking inter-actions between the phenanthroline ring systems, with centroid-centroid distances of 3.707 (9) and 3.597 (10) Å.
在标题化合物[CdI₂(C₁₄H₁₂N₂)]中，分子位于一个晶体学二重轴上。Cd(II)原子的配位球由一个2,9-二甲基-1,10-菲咯啉（dmphen）配体的两个对称等效的N原子和两个对称等效的I原子构成，从而形成一个扭曲的四面体几何构型。通过菲咯啉环系之间的π-π堆积相互作用，相关的反转分子沿c轴方向相互作用，质心间距为3.707(9)和3.597(10) Å。
Zotero 插件