Rodrigues Vinola Z, Foro Sabine, Gowda B Thimme
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2019. doi: 10.1107/S1600536811027267. Epub 2011 Jul 13.
In the title compound, C(15)H(14)ClNO, the conformation of the N-H bond is anti to the meta-methyl group in the aniline ring, while that of the C=O bond is anti to the ortho-chloro group in the benzoyl ring. The mean planes through the two benzene rings make a dihedral angle of 80.8 (2)°. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming column-like chains along the b axis.
在标题化合物C₁₅H₁₄ClNO中,N—H键的构象与苯胺环上的间甲基呈反式,而C=O键的构象与苯甲酰环上的邻氯呈反式。穿过两个苯环的平均平面形成80.8 (2)°的二面角。在晶体中,分子通过分子间N—H⋯O氢键相连,沿b轴形成柱状链。