Betz Richard, Gerber Thomas, Hosten Eric, Schalekamp Henk
Nelson Mandela Metropolitan University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth 6031, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2180. doi: 10.1107/S1600536811030042. Epub 2011 Jul 30.
The title compound, C(14)H(12)O(4), is an asymmetric substitution product of benzophenone. Both hy-droxy groups are orientated towards the O atom of the keto group. Intra-molecular as well as inter-molecular O-H⋯O hydrogen bonds can be observed in the crystal structure, with the latter connecting the mol-ecules into chains along the crystallographic b axis. C-H⋯O contacts [C⋯O = 3.3297 (18) Å] are also apparent. The closest centroid-centroid distance between two aromatic systems is 4.9186 (9) Å.
标题化合物C(14)H(12)O(4)是二苯甲酮的不对称取代产物。两个羟基均朝向酮基的O原子。在晶体结构中可观察到分子内和分子间的O-H⋯O氢键，后者将分子沿结晶学b轴连接成链。C-H⋯O接触[C⋯O = 3.3297 (18) Å]也很明显。两个芳香体系之间最接近的质心-质心距离为4.9186 (9) Å。
