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均相催化合成伯酰胺直接从伯醇和水氨。

Heterogeneously catalyzed synthesis of primary amides directly from primary alcohols and aqueous ammonia.

机构信息

Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

出版信息

Angew Chem Int Ed Engl. 2012 Jan 9;51(2):544-7. doi: 10.1002/anie.201107110. Epub 2011 Nov 23.

DOI:10.1002/anie.201107110
PMID:22109964
Abstract

In the presence of a manganese oxide based octahedral molecular sieve (OMS-2), a range of primary amides could be synthesized directly from primary alcohols and ammonia. The observed catalysis was heterogeneous, and the recovered catalyst could be reused many times without an appreciable loss of its catalytic performance.

摘要

在锰氧化物八面沸石（OMS-2）的存在下，可以直接从伯醇和氨合成一系列伯酰胺。观察到的催化是非均相的，回收的催化剂可以多次重复使用，而其催化性能没有明显损失。

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