Department of Chemical Engineering, Faculty of Sciences, University of Granada, Campus Fuentenueva s/n, 18071 Granada, Spain.
Bull Environ Contam Toxicol. 2012 Feb;88(2):290-5. doi: 10.1007/s00128-011-0479-5. Epub 2011 Nov 30.
In this paper, toxicity values of alkylpolyglucosides have been determined by applying the 24-h immobilization test with Daphnia magna, the LumiStox(®) 300 test which employs the luminescent bacteria Photobacterium phosphoreum and the test with Selenastrum capricornutum. Three alkylpolyglucosides with different alkyl chain and degree of polymerisation have been tested. For all tests, the results indicated that Vibrio fischeri was more sensitive to toxic effects from alkylpolyglucosides than was D. magna or S. capricornutum. The results demonstrate considerable variation in toxicity responses within structurally related glucose-based surfactants regardless of the species tested. The toxicity increased as the critical micelle concentration decreased, and as the alkyl chain length and resultant hydrophobicity increased.
本文应用大型溞 24 小时静止试验、采用发光细菌费氏弧菌的 LumiStox(®) 300 试验和栅列藻试验,测定了烷基多糖苷的毒性值。试验中使用了 3 种具有不同烷基链和聚合度的烷基多糖苷。所有试验的结果均表明,相对于大型溞或栅列藻,费氏弧菌对烷基多糖苷的毒性更为敏感。结果表明,即使使用相同的受试物种,基于葡萄糖的表面活性剂结构相关但毒性反应也存在明显差异。毒性随临界胶束浓度的降低、烷基链长度的增加和疏水性的增强而增大。